Photoluminescence and energy transfer of Tm3+ doped LiIn (WO4)2 blue phosphors
Identifieur interne : 000E16 ( Main/Exploration ); précédent : 000E15; suivant : 000E17Photoluminescence and energy transfer of Tm3+ doped LiIn (WO4)2 blue phosphors
Auteurs : L. Guerbous [Algérie] ; M. Derbal [Algérie, France] ; J. P. Chaminade [France]Source :
- Journal of luminescence [ 0022-2313 ] ; 2010.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Dopage.
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- mix :
Abstract
Room temperature steady and time resolved emission spectra of LiIn1-x Tmx(WO4)2 (where thulium concentration is 0, 0.5, 1, 5 and 10 at%) blue phosphors, under UV excitation energy have been investigated. The concentration quenching effect on the blue emission, due to the (WO4)-2 groups and 1G4 → 3H6 emission transition of Tm3+ were studied. Two energy transfer mechanisms are shown. The first takes place between excited (WO4) -2 groups and the 1G4 energy level of TM3+, and is mainly analyzed by phonon-assisted energy transfer. The second mechanism is due to an energy transfer from the excited Tm3+ ions to the surrounding ground state Tm3+ ions. The non-exponential decay curves of the 1G4 level observed for higher concentrations are analyzed by the Inokuti-Hirayama model. We think that the quenching effect between Tm3+ ions is mainly linked to the dipole-dipole interactions.
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Le document en format XML
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Photoluminescence and energy transfer of Tm<sup>3+</sup>
doped LiIn (WO<sub>4</sub>
)<sub>2</sub>
blue phosphors</title>
<author><name sortKey="Guerbous, L" sort="Guerbous, L" uniqKey="Guerbous L" first="L." last="Guerbous">L. Guerbous</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laser Department, Nuclear Research Center of Algiers CRNA, 2 Bd., Frantz Fanon, BP 399</s1>
<s2>Alger</s2>
<s3>DZA</s3>
<sZ>1 aut.</sZ>
</inist:fA14>
<country>Algérie</country>
<placeName><settlement type="city">Alger</settlement>
<region nuts="2">Wilaya d'Alger</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Derbal, M" sort="Derbal, M" uniqKey="Derbal M" first="M." last="Derbal">M. Derbal</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>LASICOM, Saad Dahlab University</s1>
<s2>Blida</s2>
<s3>DZA</s3>
<sZ>2 aut.</sZ>
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<wicri:noRegion>Blida</wicri:noRegion>
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<sZ>3 aut.</sZ>
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<country>France</country>
<wicri:noRegion>33608 Pessac</wicri:noRegion>
<wicri:noRegion>87 Av. A. Schweitzer</wicri:noRegion>
<wicri:noRegion>33608 Pessac</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Chaminade, J P" sort="Chaminade, J P" uniqKey="Chaminade J" first="J. P." last="Chaminade">J. P. Chaminade</name>
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<series><title level="j" type="main">Journal of luminescence</title>
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<imprint><date when="2010">2010</date>
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<seriesStmt><title level="j" type="main">Journal of luminescence</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Dipole dipole interaction</term>
<term>Doping</term>
<term>Energy levels</term>
<term>Energy transfer</term>
<term>Impurity density</term>
<term>Indium Lithium Tungstates Mixed</term>
<term>Luminescence decay</term>
<term>Phosphors</term>
<term>Photoluminescence</term>
<term>Thulium additions</term>
<term>Time resolved spectra</term>
<term>Ultraviolet radiation</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Transfert énergie</term>
<term>Dopage</term>
<term>Spectre résolution temporelle</term>
<term>Rayonnement UV</term>
<term>Concentration impureté</term>
<term>Niveau énergie</term>
<term>Déclin luminescence</term>
<term>Indium Lithium Tungstate Mixte</term>
<term>Interaction dipôle dipôle</term>
<term>Addition thulium</term>
<term>Matériau luminescent</term>
<term>Double tungstate</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
</keywords>
<keywords scheme="mix" xml:lang="en"><term>Double tungstate</term>
<term>Energy transfer</term>
<term>Photoluminescence</term>
<term>Tm3+</term>
</keywords>
</textClass>
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<front><div type="abstract" xml:lang="en">Room temperature steady and time resolved emission spectra of LiIn<sub>1-x </sub>
Tm<sub>x</sub>
(WO<sub>4</sub>
)<sub>2</sub>
(where thulium concentration is 0, 0.5, 1, 5 and 10 at%) blue phosphors, under UV excitation energy have been investigated. The concentration quenching effect on the blue emission, due to the (WO<sub>4</sub>
)<sup>-2</sup>
groups and <sup>1</sup>
G<sub>4</sub>
→ <sup>3</sup>
H<sub>6</sub>
emission transition of Tm<sup>3+</sup>
were studied. Two energy transfer mechanisms are shown. The first takes place between excited (WO<sub>4</sub>
) <sup>-2</sup>
groups and the <sup>1</sup>
G<sub>4</sub>
energy level of TM<sup>3+</sup>
, and is mainly analyzed by phonon-assisted energy transfer. The second mechanism is due to an energy transfer from the excited Tm<sup>3+</sup>
ions to the surrounding ground state Tm<sup>3+</sup>
ions. The non-exponential decay curves of the <sup>1</sup>
G<sub>4</sub>
level observed for higher concentrations are analyzed by the Inokuti-Hirayama model. We think that the quenching effect between Tm<sup>3+</sup>
ions is mainly linked to the dipole-dipole interactions.</div>
</front>
</TEI>
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<tree><country name="Algérie"><region name="Wilaya d'Alger"><name sortKey="Guerbous, L" sort="Guerbous, L" uniqKey="Guerbous L" first="L." last="Guerbous">L. Guerbous</name>
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<name sortKey="Derbal, M" sort="Derbal, M" uniqKey="Derbal M" first="M." last="Derbal">M. Derbal</name>
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<country name="France"><noRegion><name sortKey="Derbal, M" sort="Derbal, M" uniqKey="Derbal M" first="M." last="Derbal">M. Derbal</name>
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<name sortKey="Chaminade, J P" sort="Chaminade, J P" uniqKey="Chaminade J" first="J. P." last="Chaminade">J. P. Chaminade</name>
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